Alkenyl succinic anhydride.

Alkenyl succinic anhydrides (ASA) are widely used in the paper industry as paper sizing agents [1, 2]. Other common applications include: wood preservation agents [3], additives for lubricants [4], and monomers for the fabrication ofther­ mosets as the anhydride moiety can react with diamines, diols,Medicine Matters Sharing successes, challenges and daily happenings in the Department of Medicine ARTICLE: Racial Disparities in Cardiovascular Complications With Pregnancy-Induced...Jan 16, 2020 · Vertellus acquires Bercen Chemicals. Vertellus has acquired Bercen Chemicals, a maker of alkenyl succinic anhydrides and other chemicals. Bercen, founded in 1958 and based in Denham Springs ... ABSTRACT: Alkenyl succinic anhydrides (ASA) were prepared by an -ene reaction of n-alkyl (C1 to C5) oleates with maleic an-hydride. The purified compounds were characterized by FTIR, 1H NMR, and MS analytical methods to elucidate their struc-tures.The reaction between acetic anhydride and water is written as follows: (CH3CO)2O + H2O – 2CH3COOH. This reaction produces two molecules of etanoic acid, a compound that appears as ...

Succinic Anhydride. 113 Alkenyl succinic anhydrides (extensively used in the papermaking industry as paper sizing agents when manufactured by reaction of maleic anhydride with C14–C22 i-olefins) have been prepared by the ene reaction of the methyl esters of high-oleic sunflower oil with maleic anhydride in a 50% xylene medium.

Alkenyl succinic anhydride (ASA) sizing is dominating over other sizing processes due to its high reactivity and economy. The shelf life of conventionally used cationic starch (CS) … Cellulosic fiber is hydrophilic in nature and making it hydrophobic represents a process called sizing in papermaking.The global alkenyl succinic anhydride (ASA) market size reached USD 247.9 million in 2022 and will readjusted size of USD 302.48 million by 2031, at CAGR of 2.2% during the forecast period. The alkenyl succinic anhydride (ASA) market growth is attributed to several key factors. Firstly, the increasing demand for high-performance sizing agents ...

Alkenyl succinic anhydride is used mainly in neutral and alkaline papermaking. It is usually mixed with cationic starch, polyacrylamide, or fluorescent carbon dots to form a stable emulsion before being added to pulp. Adding the ASA emulsion into the wet end of the paper machine in-Sep 3, 2021 ... Kemira announces a significant investment in the production of alkenyl succinic anhydride sizing agent (ASA) in China. ASA is one of the ...The global Alkenyl Succinic Anhydride (ASA) market size was valued at USD 203.82 Million in 2022 and will reach USD 299.58 Million in 2028, with a CAGR of 6.63% during 2024-2030. The Global ...Alkenyl succinic anhydride (ASA) is a reactive sizing agent that can impart good water repellence to paper by decreasing the wettability of the cellulose fibers. However, ASA can undergo ...The alkenyl succinic anhydrides are valuable precursors for the preparation of alkyl succinic anhydrides. ABSTRACT A process for producing alkenyl succinic anhydrides by the reaction of an olefin with maleic anhydride in …

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Jan 14, 2013 · Alkenyl succinic anhydride (ASA) is a viscous polar oil, typically used as a paper sizing agent after being emulsified. ASA and water emulsions stabilized by TiO 2 nanoparticles were prepared by adding the aqueous phase to the oil phase. Catastrophic phase inversion from w/o to o/w or w/o/w has been investigated by monitoring the variation of ...

PDF. Abstract. Alkenyl succinic anhydride (ASA) is one of the most prominent paper sizing agents worldwide. Commercial products start from isomerized C16-18 olefins with …Alkenyl succinic anhydrides (ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso- alkenyl chain (C 14 to C 22 ). ASA's are colorless and usually viscous liquids.Alkenyl succinic anhydride (ASA) is one of the most prominent paper sizing agents worldwide. Commercial products start from isomerized C16-18 olefins with certain distribution of the double bond along the alkyl chain. This distribution is then found again in the product ASA which renders mechanistic studies on ASA binding to the cellulose … Cationic starch and polyacrylamides for alkenyl succinic anhydride (ASA) emulsification for sizing of cellulosic fibers. Paper is composed of polysaccharides mainly cellulose and carbohydrates. The hydroxyl groups present in cellulose react with various substances added to fibrous slurry. Treating the cellulosic fibers…. alkenyl succinic anhydride; emulsion; stability; Acknowledgements. The authors are grateful for the financial provided by the National Natural Science Foundation of China (52172147), the Natural Science Foundation of Shandong Province (ZR2022MB095), Shandong Province Key Research and Development Program (2021ZDSYS18), and the …Jun 29, 2023 · Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose.

Among them, alkenyl succinic anhydride (ASA) is a commonly applied neutral sizing agent, and needs to be prepared as an oil-in-water emulsion before sizing (Guodong Li et al. 2017; Yu et al. 2020).Jun 1, 2017 · Stabilizing alkenyl succinic anhydride (ASA) emulsions using fine particles instead of cationic starch have attracted much attention in recent years. Herein, starch nanocrystals (SNCs) made from maize starch by H 2 SO 4 hydrolysis were used to co-stabilize ASA emulsions with fluorescent carbon dots (CDs) made hydrothermally from gelatin. Hydrophobically modified inulin from alkenyl succinic anhydride in aqueous media @article{Morros2011HydrophobicallyMI, title={Hydrophobically modified inulin from alkenyl succinic anhydride in aqueous media}, author={Jordi Morros and Bart Levecke and Mar{\'i}a Rosa Infante}, journal={Carbohydrate Polymers}, year={2011}, volume= {84 ...It is well known that alkenyl succinic anhydride (ASA), an alkaline sizing agent, when applied to cellulosic fibers will impart a resistance to the absorption of … Product name : Succinic anhydride Product Number : 239690 Brand : Aldrich Index-No. : 607-103-00-5 CAS-No. : 108-30-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Synthesis of substances

Cashew gum (CG) shows promise of being useful as an agro-based raw material for the production of eco-friendly and biodegradable polymers. In this work, we modified this water-soluble polymer with alkenyl succinic anhydride in order to attach a hydrophobic group to it. The modification used two reagents: octenyl succinic anhydride and tetrapropenyl succinic anhydride. Reactions were conducted ...

Stabilizing alkenyl succinic anhydride (ASA) emulsions using fine particles instead of cationic starch have attracted much attention in recent years. Herein, starch nanocrystals (SNCs) made from maize starch by H 2 SO 4 hydrolysis were used to co-stabilize ASA emulsions with fluorescent carbon dots (CDs) made hydrothermally from gelatin.Autism symptoms are actually differences in sensory, communication, and behavior patterns. Here's why. Signs of autism spectrum disorder include differences in communication and be...To grow new African violets, use a sterile knife and cut off a healthy leaf as near the base as possible. Dip the stem in rooting hormone then push it through a piece of paper and ...Jul 10, 2000 · DOI: 10.2115/FIBER.56.334 Corpus ID: 99496439; The reason why the reactive chemical structure of alkenyl succinic anhydride is necessary for efficient paper sizing @article{Isogai2000TheRW, title={The reason why the reactive chemical structure of alkenyl succinic anhydride is necessary for efficient paper sizing}, author={Akira Isogai}, journal={Sen-i Gakkaishi}, year={2000}, volume={56 ... Paper sizing (Elevexx™ 1600 AO, 1800 AO): Linear alpha olefin is the hydrophobic component in alkenyl succinic anhydride (ASA), primarily used as an internal sizing agent. ASA inhibits water absorption and control the spread of inks into paper and board. Other applications for ASAs include fuel and lube additives, food modifiers, epoxy resins ...Short description of key information: The substance has been tested in a guideline bacterial reverse mutation assay and found to be negative (not mutagenic). Other members of the C8-12 Alkenyl Succinic Anhydride category have also been nonmutagenic in in vitro genotoxicity tests. The conclusion is that the substance is not genotoxic.May 15, 2020 · Alkenyl succinic anhydride (ASA) sizing is dominating over other sizing processes due to its high reactivity and economy. The shelf life of conventionally used cationic starch (CS) … Cellulosic fiber is hydrophilic in nature and making it hydrophobic represents a process called sizing in papermaking. To improve the amphipathic property of glucuronoxylans and develop high quality natural-based/green emulsifiers, glucuronoxylans were chemically modified by alkenyl succinic anhydrides to produce a novel emulsifer.Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the chemical in papermaking, scientists still have differing views on how ASA interacts with cellulose. Several experiments were conducted to bring more clarity to the ASA sizing …Quantity Value Units Method Reference Comment; Δ r H°-46.86 ± 0.08: kJ/mol: Cm: Conn, Kistiakowsky, et al., 1942: liquid phase; Heat of hydrolysis at 303 K

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Alkenyl succinic anhydrides ( ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso- alkenyl chain (C 14 to C 22 ). ASA's are colorless and usually viscous liquids. They are widely used, especially in surface sizing of paper, paperboard, and cardboard, as well as in the hydrophobicization of ...

Alkenyl succinic anhydride (ASA) was a commercial product of Dixie Chemical Co., Inc (Pasadena, Texas, US). It is an amber liquid with a density of 0.947 g/cm 3 at 25 °C. According to the supplier’s specification, the ASA is composed of 94.9 wt% of octadecenylsuccinic anhydride (C 22 H 38 O 3 ), 3.38 wt% of hexadecenylsuccinic anhydride (C ...Tree gums are a class of abundantly available carbohydrate polymers that have not been explored thoroughly in film fabrication for food packaging. Films obtained from pristine tree gums are often brittle, hygroscopic, and lack mechanical strength.This study focuses on the chemical modification of gum kondagogu using long-chain alkenyl groups … 2 -Dodecenyl succinic anhydride is classified as a severe skin irritant, Category 2, according to Regulation EC No. 1272/2008. The substance is classified as an eye irritant, Category 2, by "reading-across" from tetrapropenyl succinic anhydride, a member of the C8 -12 Alkenyl Succinic Anhydride category. Films obtained from pristine tree gums are often brittle, hygroscopic, and lack mechanical strength. This study focuses on the chemical modification of gum kondagogu using long-chain alkenyl groups of dodecenyl succinic anhydride (DDSA), an esterifying agent that introduces a 12-carbon hydrophobic chain to the kondagogu structure.Abstract Alkenyl succinic anhydride (ASA) is widely used in papermaking industry as an internal sizing agent. In situ emulsication of ASA using cati-onic starch is conventionally practiced because of the low shelf life of ASA emulsion. We synthesized Janus particles by surfactant-free seeded polymerization to stabilize ASA emulsion.CELLULOSE STRUCTURE HYDROPHOBIZATION BY ALKENYL SUCCINIC ANHYDRIDE (ASA) – A Novel Approach to Performance Explanation a presentationby S. Porkert, Munich University of Applied Sciences S ...Alkenyl succinic anhydrides (ASA) have been prepared by ene-reaction of high-oleic sunflower oil methyl esters with maleic anhydride in a 50% xylene medium. …Alkenyl Succinic Anhydride (ASA) Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH’s in the range of 7.5-8.5) in the 1960’s by O. Wurzburg and E. Mazzerella of the National Starch and Chemical Company [1].Alkenyl succinic anhydride (ASA) is one of the most prominent paper sizing agents worldwide. Commercial products start from isomerized C16-18 olefins with certain distribution of the double bond ...Alkenyl succinic anhydride (ASA) is a viscous polar oil, typically used as a paper sizing agent after being emulsified. ASA and water emulsions stabilized by TiO 2 nanoparticles were prepared by adding the aqueous phase to the oil phase. Catastrophic phase inversion from w/o to o/w or w/o/w has been investigated by monitoring the variation of ...On the heels of the Farecast post from earlier today, I looked around and realized that we've never asked you how you do airline travel on the cheap. On the heels of the Farecast p...Alkenyl succinic anhydride (ASA) is an internal sizing chemical, normally applied in paper and board making at roughly neutral pH. For the paper and paperboards which have huge proportion of secondary fibers and mechanical cellulosic pulp, ASA has the advantage in sizing.

Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under …The invention discloses a preparation method of alkenyl succinic anhydrides (ASA). The preparation method comprises the following steps of: mixing raw materials (internal olefins and maleic anhydride in the molar ratio of 1.0 to 4.0), reacting the raw materials for 10-20 hours by using silica gel or silicate as a catalyst at a reaction temperature of 150 …Alkenyl succinic anhydride (ASA) was a commercial product of Dixie Chemical Co., Inc (Pasadena, Texas, US). It is an amber liquid with a density of 0.947 g/cm 3 at 25 °C. According to the supplier’s specification, the ASA is composed of 94.9 wt% of octadecenylsuccinic anhydride (C 22 H 38 O 3 ), 3.38 wt% of hexadecenylsuccinic anhydride (C ...Instagram:https://instagram. yahoo email inbox May 10, 2024 · As of 2022, the global Alkenyl Succinic Anhydride (ASA) market was estimated at USD 203.82 million, and it’s anticipated to reach USD 299.58 million in 2028, with a CAGR of 6.63% during the ... sign language learning Here, an easy-fabricating, stable, and high-performance alkenyl succinic anhydride (ASA) paper-sizing emulsion is developed, which is stabilized by lauric arginate (LAE)/cellulose nanocrystal (CNC ...Alkenyl Succinic Anhydride (ASA) is basic or neutral type sizing agent. It is wax like chemicals. ASA is used as internal sizing chemicals for paper. Structurally, it is unsaturated linear chain having five-membered anhydride ring and it is synthesized from Alfa-olefins and maleic anhydride. The anhydride ring has no fixd position in the chain ... photo of book Alkenyl Succinic Anhydride (ASA) is a sizing agent used in papermaking to increase the water repellency of paper. Almost 60 years after the introduction of the … Cationic starch and polyacrylamides for alkenyl succinic anhydride (ASA) emulsification for sizing of cellulosic fibers. Paper is composed of polysaccharides mainly cellulose and carbohydrates. The hydroxyl groups present in cellulose react with various substances added to fibrous slurry. Treating the cellulosic fibers…. how to recover deleted voicemail Among them, alkenyl succinic anhydride (ASA) is a commonly applied neutral sizing agent, and needs to be prepared as an oil-in-water emulsion before sizing … 53 banking login This study focuses on the chemical modification of gum kondagogu using long-chain alkenyl groups of dodecenyl succinic anhydride (DDSA), an esterifying agent that introduces a 12‑carbon ... z88.3 fm radio Alkenyl succinic anhydride (ASA) is a reactive sizing agent that can impart good water repellence to paper by decreasing the wettability of the cellulose fibers. However, ...Those results indicate that this surface strategy with DMSO as the pre-swelling solvent and the long-chain alkenyl succinic anhydride as the acylants (especially OSA) is particularly feasible for improving the properties of various types of BC films, which display great potential to be used in value-added applications, such as food packaging or biomedical … best western culpeper va Alkenyl succinic anhydrides (ASA) were prepared by an-ene reaction of n-alkyl (C 1 to C 5) oleates with maleic anhydride. The purified compounds were characterized by FTIR, 1 H NMR, and MS analytical methods to elucidate their structures.The alkenyl succinic anhydride (ASA) market is mainly driven by growing demand for sizing agent for paper. ASA minimizes water absorption and enhances the surface conditions of paper during a neutral paper manufacturing process. In the paper industry, alkyl succinic anhydrides market plays a significant role in minimizing the harmful ...Succinic anhydride appears as colorless needles or white crystalline solid. Melting point 237 °F. Sublimes at 239 °F at 5 mmHg pressure; and at 198 °F and 1 mmHg pressure. Moderately toxic and an irritant. CAMEO Chemicals. Succinic anhydride is a cyclic dicarboxylic anhydride and a tetrahydrofurandione. webp format to jpg Alkenyl succinic anhydrides (ASA) are derivatives of succinic anhydrides. One H of the succinic anhydride ring is replaced with an iso- alkenyl chain (C 14 to C 22 ). ASA's are colorless and usually viscous liquids. prudhoe bay hotel Alkenyl succinic anhydride (ASA) is commonly used in the neutral/alkaline papermaking process. It is an oily monomer and is added to pulp stock in a form of aqueous emulsion at room temperature. It provides on machine sizing because of its high degree of reactivity with the hydroxyl groups on polysaccharide components in the paper substrate [1]. dimensions of youtube banner 2 -Dodecenyl succinic anhydride is classified as a severe skin irritant, Category 2, according to Regulation EC No. 1272/2008. The substance is classified as an eye irritant, Category 2, by "reading-across" from tetrapropenyl succinic anhydride, a member of the C8 -12 Alkenyl Succinic Anhydride category.The optimal reaction conditions for obtaining the maximal yield (around 95%) of alkenyl succinic anhydride from methyl oleate were 235°C, a molar ratio of 1.5, and a reaction lasting 8 h. However, the products synthesized under these conditions showed high viscosity (215 cP), a very dark color (18+ Gardner color), and a high content of ... free mbl Mar 14, 2022 · Among them, alkenyl succinic anhydride (ASA) is a commonly applied neutral sizing agent, and needs to be prepared as an oil-in-water emulsion before sizing (Guodong Li et al. 2017; Yu et al. 2020). In the traditional emulsifying process, the excessive use of surfactants can facilitate emulsification, but that will have an adverse effect on ... Alkenyl succinic anhydrides are important specialty chemicals that are used in the paper, oilfield, and fuel additives industries. In this paper we investigate the link …Alkenyl succinic anhydride (ASA) is a viscous polar oil, typically used as a paper sizing agent after being emulsified. ASA and water emulsions stabilized by TiO 2 nanoparticles were prepared by adding the aqueous phase to the oil phase. Catastrophic phase inversion from w/o to o/w or w/o/w has been investigated by monitoring the …